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References

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Poon, W. C. K. and Pusey, P. N., in Observation, Prediction and Simulation of Phase Transitions in Complex Fluid, edited by Baus, M., Rull, L. F. and Ryckaert, J. P., pp3-44, Kluwer Academic Publishers, 1994.

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Asakura, S. and Oosawa, F., J. Chem. Phys., 22, 1255 (1954).

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Asakura, S. and Oosawa, F., J. Polym. Sci., 33, 183 (1958).

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Walz, J. Y. and Sharma, A., J. Coll. and Interface Sci., 168, 485 (1994).

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Mao, Y., Cates, M. E. and Lekkerkerker, H. N. W., Physica A, 222, 10 (1995).

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Mao, Y., J. de Phys. II (France), 5, 1761 (1995).

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Mao, Y., Cates, M. E. and Lekkerkerker, H. N. W., Phys. Rev. Lett., 75, 4548 (1995).

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Attard, P., J. Chem. Phys., 91 3083 (1989).

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Evans, R., Henderson, J. R., Hoyle, D. C., Parry, A. O. and Sauber, Z. A., Molec. Phys. 80, 755 (1993).

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Bolhuis, P. and Frenkel, D., J. Chem. Phys., 101, 9869 (1994).

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Tracy, M. A., Garcia, J. L. and Pecora, R., Macromolecules, 26, 1862 (1993). It is possible that the sphere concentration in this study was not high enough to cross the phase boundary.

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Lenferink, J., Verhaegh, N. A. M. and Lekkerkerker, H. N. W., unpublished experiments on mixtures of colloidal spheres and rods.

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Mao, Y., Lekkerkerker, H. N. W. and Cates, M. E., in preparation.

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Russel, W. B., Saville, D. A. and Schowalter, W. R., Colloidal Dispersions, Cambridge University Press, Cambridge 1989.

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Holyst, R., Molec. Phys., 68, 391 (1989).

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Henderson, J. R., Molec. Phys., 59, 89 (1986).

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Widom, B., J. Chem. Phys., 39, 2808 (1963); J. Stat. Phys., 19, 563 (1978).

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Figure Captions

Fig.1. Two rods between two infinite parallel plates.

Fig.2. The dimensionless functions tex2html_wrap_inline978 , allowing the determination of the depletion potential to third order in density for arbitrary parameters.

Fig.3(a-d). Plots of typical depletion force tex2html_wrap_inline718 in units of tex2html_wrap_inline1186 . The plots a-d correspond to reduced densities tex2html_wrap_inline1098 respectively. Lines: 2nd order perturbation results. Dashed lines: 3rd order perturbation results. Dots: numerical solutions of the full integral equation.

Fig.4(a-d). Plots of typical depletion potential tex2html_wrap_inline1190 in units of tex2html_wrap_inline686 , for R/L=10, L/D=20. The plots a-d correspond to reduced densities tex2html_wrap_inline1098 respectively. Lines: 2nd order perturbation results. Dashed lines: 3rd order perturbation results. Dots: numerical solutions of the full integral equation.

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Yong Mao
Tue Sep 17 16:40:38 BST 1996