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Next: Appendix: Pressure Sum Rule Up: Theory of the Depletion Previous: Discussion

Summary

We have presented an integral equation, exact in the limit of long thin rods, whose numerical solution we used to predict the depletion force between parallel plates, and that between large spheres, due to rod-like colloidal particles in semidilute solution. The results were compared with our previous perturbation treatment, showing good agreements at low densities (confirming the numerics) but also the gradual failure of perturbation theory as the density goes up. From the numerical results, we concluded that the depletion barrier is typically less than the thermal energy tex2html_wrap_inline686 , and therefore unlikely to significantly alter the phase diagram of colloidal sphere-rod mixtures, either in equilibrium or kinetically. Compared to the simplest first order results, the main correction from the full numerical results is to modify the depth and the range of the primary depletion well. The same method allows predictions for the surface tension of rod solutions to be made, along the lines suggested in Ref.[19]; see Ref.[13]. In principle our treatment could be extended to the nematic phase of rods, but the reduced symmetry of the integral kernel will make this numerically unfeasible; indeed even for the isotropic case the maximum density of rods we could achieve was only about half that of a nematic solution. All our results are subject to corrections of order D/L, the inverse aspect ratio of the rods, which may be significant for realistic values of this quantity and which remain to be quantified in detail.

Acknowledgements: We thank R. C. Ball, M. E. Fisher, C.-Y. D. Lu, H. P. Marro, J. Melrose, P. van der Schoot, and M. S. Turner for useful discussions. Y.M. is grateful to Trinity College for a Research Studentship. This collaboration was funded in part by the Colloid Technology Programme. MEC is grateful to the Isaac Newton Institute for Mathematical Sciences (Cambridge) where part of this work was completed.


next up previous
Next: Appendix: Pressure Sum Rule Up: Theory of the Depletion Previous: Discussion

Yong Mao
Tue Sep 17 16:40:38 BST 1996